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Standard Practice for On-Line Determination of Cation Conductivity in High Purity Water

ASTM D6504-11

Organization:
ASTM - ASTM International
Year: 2024

Abstract: 5.1 Cation conductivity provides one of the most sensitive and dependable on-line means of detecting anionic contamination in the boiler/steam cycle, such as chlorides, sulfates, nitrates, bicarbonates, and organic acids, such as formic and acetic. 5.2 High sensitivity is provided by intentionally eliminating the pH adjusting treatment chemical(s), for example, ammonia and amines, from the sample and converting remaining salt contaminants into their acid forms which are approximately three times as conductive. 5.3 Guidelines on cation conductivity limits for various cycle chemistry and boiler types have been established by EPRI (2-4) and by ASME (5 and 6). 5.4 The sample effluent from the cation exchange column also may be used, and in some cases is preferred, for ion chromatography or other anion measurements.
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    Standard Practice for On-Line Determination of Cation Conductivity in High Purity Water

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contributor authorASTM - ASTM International
date accessioned2024-12-17T23:28:15Z
date available2024-12-17T23:28:15Z
date copyright2024
date issued2024
identifier otherD6504-11r24.pdf
identifier urihttp://yse.yabesh.ir/std;jsessionid=8618CD0F39F0B9B5E782DA709FC20E0E/handle/yse/337771
description abstract5.1 Cation conductivity provides one of the most sensitive and dependable on-line means of detecting anionic contamination in the boiler/steam cycle, such as chlorides, sulfates, nitrates, bicarbonates, and organic acids, such as formic and acetic. 5.2 High sensitivity is provided by intentionally eliminating the pH adjusting treatment chemical(s), for example, ammonia and amines, from the sample and converting remaining salt contaminants into their acid forms which are approximately three times as conductive. 5.3 Guidelines on cation conductivity limits for various cycle chemistry and boiler types have been established by EPRI (2-4) and by ASME (5 and 6). 5.4 The sample effluent from the cation exchange column also may be used, and in some cases is preferred, for ion chromatography or other anion measurements.
languageEnglish
titleStandard Practice for On-Line Determination of Cation Conductivity in High Purity Wateren
titleASTM D6504-11num
typestandard
page6
statusActive
treeASTM - ASTM International:;2024
contenttypefulltext
scope1.1 This practice describes continuous sample conditioning by hydrogen ion exchange and measurement by electrolytic conductivity. It is commonly known as cation conductivity measurement in the power industry although it is actually an indication of anion contamination in high purity water samples. Measurements are typically in a range less than 1 μS/cm. 1.2 The actual conductivity measurements are made using Test Method D5391. 1.3 This practice does not provide for separate determination of dissolved carbon dioxide. Refer to Test Method D4519. 1.4 The values stated in SI units are to be regarded as standard. The values given in parentheses are mathematical conversions to inch-pound units that are provided for information only and are not considered standard. 1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use. 1.6 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
identifier DOI10.1520/D6504-11R24
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