NACE SP0775

Abstract

General This standard is presented for the use of corrosion coupons in oilfield drilling, production, and transportation operations. Oilfield operations include oil-, water-, and gas-handling systems, and drilling fluids. (When used in this standard, system denotes a functional unit such as a producing well; flowline and tank battery; water, oil, or gas collection facility; water or gas injection facility; or a gas dehydration or sweetening unit.) Corrosion coupon testing consists of the exposure of a small specimen of metal (the coupon) to an environment of interest for a period of time to determine the reaction of the metal to the environment. Corrosion coupons are used to evaluate corrosiveness of various systems, to monitor the effectiveness of corrosion-mitigation programs, and to evaluate the suitability of different metals for specific systems and environments. The coupons may be installed in the system itself or in a special test loop or apparatus. Corrosion rates shown by coupons and most other corrosion-monitoring devices seldom duplicate the actual rate of corrosion on the system piping and vessels. Accurate system corrosion rates can be determined by nondestructive measurement methods or failure frequency curves. Data furnished by corrosion coupons and other types of monitors must be related to system requirements. High corrosion rates on coupons may be used to verify the need for corrective action. If a corrosion-mitigation program is initiated and subsequent coupon data indicate that corrosion has been reduced, the information can be used to approximate the effectiveness of the mitigation program. This standard does not contain information on monitoring for intergranular corrosion, stress corrosion cracking (SCC), or sulfide stress cracking (SSC). The latter aspects are discussed elsewhere.1,2  This standard describes preparation and handling techniques for metal coupons prior to and following exposure. Corrosion rate calculations and a typical form for recording data are also included.  Coupon size, metal composition, surface condition, and coupon holders may vary according to the test system design or the user’s requirements. Coupons are often installed in pairs for simultaneous removal and average mass-loss determination. Coupons may be used alone but they should be used in conjunction with other monitoring methods such as test nipples, hydrogen probes, galvanic probes, polarization instruments, resistance-type corrosion monitors, chemical analysis of process streams and nondestructive metal thickness measurements, caliper surveys, and corrosion failure records.  Corrosion coupons used as recommended in this standard measure the total metal loss during the exposure period. They show corrosion that has already occurred. A single coupon cannot be used to determine whether the rate of metal loss was uniform or varying during the exposure period. Information on the change in corrosion rate can be obtained by installing several coupons at one time and removing and evaluating individual coupons at specific short-term intervals. Other monitoring methods mentioned in Paragraph 1.3 can be used to provide more accurate information on short-term rates of corrosion. Data provided by corrosion coupons can provide excellent backup for “event-indicating” corrosion- monitoring instruments.  In addition to mass loss, important factors to consider in the analysis and interpretation of coupon data include location, time on stream, measured pit depth, surface profile (blistering, erosion), corrosion product and/or scale composition, and operating factors (e.g., downtime, system flow velocities, upsets, or inhibition).